陈爱军，张喜利，张云莉，贺福元，刘 珊，刘文龙*，刘平安

    (1湖南环境生物职业技术学院，湖南衡阳421005；2湖南中医药大学中药超分子实验室，湖南长沙410208；3.湖南安乡县北河口血防站，湖南常德415600)

    ·药物分析·

    葡萄糖原料碎米中12种有机磷农药残留快速检测

    陈爱军1，2，张喜利2，张云莉3，贺福元2，刘珊2，刘文龙2*，刘平安2

    (1湖南环境生物职业技术学院，湖南衡阳421005；2湖南中医药大学中药超分子实验室，湖南长沙410208；3.湖南安乡县北河口血防站，湖南常德415600)

    目的建立一种快速检测碎米中有机磷农药残留量的方法，用于注射用葡萄糖原料碎米的质量监控。方法采用气相色谱法与氮磷检测器(NPD)快速检测碎米中的12种农药残留。结果所建立的方法学的线性范围是0.1～5.0 ppm、检出限为0.98～6.24 ppb、检测限为3.27～20.8 ppb、相关系数均大于0.999 5；精密度、重复性的RSD均在6.3%以下；回收率在87.25%～108.4%。结论本文建立了碎米中有机磷农药残留的快速检测方法，为注射用葡萄糖的制备筛选出合格的碎米原料提供了有效保障。

    碎米；注射用葡萄糖；气相色谱；有机磷农药残留

    〔Abstract〕objective To establish a determination method of the organophosphate in the broken rice，which can be used to control the glucose-injection quality.M ethods 12 kinds of pesticides residues were rapid detected by using gas chromatography adding NDP detector.Results The linear range in the established determination method was 0.1～5.0 ppm，the limit of detection was 0.98～6.24 ppb，the limit of qualification was 3.27～20.8 ppb，and the correlation coefficient were all more than 0.995.Furthermore，the RSDs of the precision and repeatability tests were under 6.3% ......